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This Week's TV: The Biggest Wasted Opportunity in Ages. Plus Brand New Venture Bros.!

This week on TV, the Venture Bros. are celebrating Halloween in their own unique style. There's the single best cast of a Syfy Original Movie you could possibly imagine, including one Star Trek star and Ernest Hemingway's grandkid. One of DC Comics' coolest characters is coming to Arrow, and Buzz Aldrin is playing…